{"id":4532,"date":"2024-10-12T10:05:04","date_gmt":"2024-10-12T02:05:04","guid":{"rendered":"https:\/\/www.bdma.com.cn\/?p=4532"},"modified":"2024-10-12T10:05:04","modified_gmt":"2024-10-12T02:05:04","slug":"%e5%a6%82%e4%bd%95%e5%90%88%e6%88%90%e6%b0%a7%e7%a9%ba%e4%bd%8d%ef%bc%9f","status":"publish","type":"post","link":"https:\/\/www.bdma.com.cn\/archives\/4532","title":{"rendered":"\u5982\u4f55\u5408\u6210\u6c27\u7a7a\u4f4d\uff1f"},"content":{"rendered":"

\u5982\u4f55\u5408\u6210\u6c27\u7a7a\u4f4d<\/strong><\/a>\uff1f<\/p>\n

a. \u8fd8\u539f\u5904\u7406<\/p>\n

\u8fd8\u539f\u6c14\u4f53\u8fd8\u539f<\/p>\n

\u5728\u9ad8\u6e29\u6216\u538b\u529b\u6761\u4ef6\u4e0b\u91d1\u5c5e\u6c27\u5316\u7269\u7684CO\u3001NH3\u3001H2\u7b49\u5904\u7406\u662f\u7531\u4e8e\u8fd8\u539f\u6c14\u7684\u5f3a\u7684\u8fd8\u539f\u6027\u5f15\u8d77\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u7684\u7f3a\u9677\u662f\u5e38\u89c1\u7b56\u7565\u3002\u901a\u8fc7\u8c03\u8282\u6e29\u5ea6\u3001\u538b\u529b\u3001\u6c14\u4f53\u7ec4\u6210\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u751f\u4ea7\u5177\u6709\u4e0d\u540c\u7a0b\u5ea6\u548c\u4e0d\u540c\u00a0 \u00a0 \u6d53\u5ea6\u7684OVS\u3002<\/p>\n

\"\u5982\u4f55\u5408\u6210\u6c27\u7a7a\u4f4d\uff1f\u63d2\u56fe\"<\/p>\n

\u6d3b\u6027\u91d1\u5c5e\u8fd8\u539f\u5242<\/p>\n

\u65e0\u673a\u7269NaBH4 \u3001CaH2\u6709\u673a\u7269\u54aa\u5511\u548cL-\u6297\u574f\u8840\u9178\u7b49\u5904\u7406\u3002\u4f8b\u5982\u5229\u7528\u5177\u6709\u5f3a\u8fd8\u539f\u6027\u91d1\u5c5eLi, Mg, Al , Zn\uff0c\u8fdb\u884c\u6293\u53d6\u6c27\u5316\u7269\u4e2d\u7684\u6676\u683c\u6c27\u4f7f\u5176\u4ea7\u751f\u7f3a\u9677\u3002\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u78b3\u9178\u4e8c\u7532\u916f\uff08DMC\uff09\u6df7\u5408\u7684Li\u7c89\u672b\u7ec4\u6210\u3002\u5c06\u6df7\u5408\u7269\u7814\u78e81\u5c0f\u65f6\u5e76\u901a\u8fc7\u8c03\u8282Li\u7c89\u672b\u542b\u91cf\uff080-5wt%\uff09\uff0c\u5177\u6709\u4e0d\u540c\u6d53\u5ea6\u7684\u7f3a\u9677\uff0c\u5176\u7279\u5f81\u5728\u4e8e\u9010\u6e10\u8f83\u6697\u7684\u989c\u8272\uff0c\u5728\u8be5\u8fc7\u7a0b\u4e2d\uff0cLi\u9664\u53bb\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u6c27\u6c14\uff0c\u5f62\u6210\u6b64\u65b9\u6848\u4e3a\u5ba4\u6e29\u4e0b\u4ea7\u751f\u7f3a\u9677\u6c27\u5316\u7269\u3002<\/p>\n

\u7535\u5316\u5b66\u8fd8\u539f\u5904\u7406<\/p>\n

\u5728\u7535\u5316\u5b66\u8fd8\u539f\u8fc7\u7a0b\u4e2d\uff0c\u91d1\u5c5e\u79bb\u5b50\u63a5\u53d7\u5916\u90e8\u7535\u5b50\u4ee5\u5f62\u6210\u4f4e\u4ef7\u91d1\u5c5e\u79bb\u5b50\u3002\u4e3a\u4e86\u8865\u507f\u7535\u8377\u5e73\u8861\uff0c\u4ea7\u751f\u6c27\u6c14\u7a7a\u4f4d\uff0c\u5e76\u4e14\u7535\u89e3\u8d28\u4e2d\u9759\u6001\u9633\u79bb\u5b50\uff08C +\uff09\u5d4c\u5165\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u3002\u8be5\u673a\u5236\u53ef\u4ee5\u6982\u62ec\u4e3a<\/p>\n

b. \u9ad8\u80fd\u7c92\u5b50\u8f70\u51fb<\/p>\n

\u7b49\u79bb\u5b50\u4f53\u548c\u9ad8\u80fd\u8d28\u5b50\u7684\u9ad8\u80fd\u91cf\u9897\u7c92\u53ef\u4ee5\u5f3a\u70c8\u5730\u4e0e\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u4e0a\u7684\u539f\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u5bfc\u81f4\u7814\u7a76\u4eba\u5458\u62a5\u544a\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u7684\u8868\u9762\u7ed3\u6784\u635f\u574f\u548c\u6c27\u7a7a\u4f4d\u7684\u7f3a\u6c27\u7a7a\u4f4d\u3002\u65bd\u52a0\u7684\u9ad8\u80fd\u8d28\u5b50\u79bb\u5b50\u690d\u5165\u4ee5\u6539\u53d8TiO2\u7eb3\u7c73\u7ba1\u7684\u8868\u9762\uff0c\u8bf1\u5bfc\u7279\u5b9a\u7f3a\u9677\u3002<\/p>\n

\"\u5982\u4f55\u5408\u6210\u6c27\u7a7a\u4f4d\uff1f\u63d2\u56fe1\"<\/p>\n

c. \u771f\u7a7a\u7145\u70e7\u5904\u7406<\/p>\n

\u901a\u8fc7\u5728100\u2103\u4ee5\u4e0a\u7684\u9ad8\u6e29\u4e0b\u5c06\u65e0\u7f3a\u9677\u91d1\u5c5e\u6c27\u5316\u7269\u653e\u5165\u771f\u7a7a\u7089\uff0c\u5b9e\u73b0\u7145\u70e7\u771f\u7a7a\u6d3b\u5316\u4ee5\u83b7\u5f97\u6c27\u7a7a\u4f4d\u7f3a\u9677\u7ed3\u6784\u3002\u8fd9\u79cd\u7f3a\u6c27\u7684\u5927\u6c14\u4e2d\u4ea7\u751f\u4e86\u6c27\u7a7a\u4f4d\u548c\u4f4e\u4ef7\u91d1\u5c5e\u79bb\u5b50\u3002<\/p>\n

d. \u8d85\u58f0\u6ce2\u5904\u7406<\/p>\n

\u4f7f\u7528\u5177\u6709\u9ad8\u529f\u7387\u5bc6\u5ea6\u7684\u8d85\u58f0\u6ce2\u4f7f\u5176\u91d1\u5c5e\u6c27\u5316\u7269\u8868\u9762\u65e0\u5e8f\u5316\uff0c\u6539\u53d8\u7535\u5b50\u7ed3\u6784\u4ece\u800c\u4ea7\u751f\u6c27\u7a7a\u4f4d<\/p>\n

e. \u6eb6\u80f6\u51dd\u80f6\u7f9f\u57fa\u5316<\/p>\n

\u6851\u6770\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u9505\u51dd\u80f6\u71c3\u70e7\u5408\u6210\u7b56\u7565(J. Mater. Chem. A,2016, 4, 5854\u20135858)\u3002\u5c060.4M\u4e01\u9187\u5316\u949b\u4e0e50mL\u7684\u4e8c\u4e59\u4e8c\u9187(DEG)\u6df7\u5408\uff0c\u5f62\u6210\u9ec4\u8272\u7cd6\u4e8c\u9178\u949b\u590d\u5408\u7269\u51dd\u80f6\u3002\u52a0\u516514.4mL\u6c34\u5e76\u6405\u62cc15\u5206\u949f\u7136\u540e\u5c06\u6c34\u5408\u7684\u7cd6\u4e8c\u9178\u949b\u51dd\u80f6\u4fdd\u6301\u5728300\u2103 2h\u3002\u52a0\u5165\u8fc7\u91cf\u7684\u6c34\u786e\u4fdd\u4e8c\u6c27\u5316\u949b\u6709\u8db3\u7684\u7f9f\u57fa\u5316\uff0c\u8fc7\u91cf\u7684\u7f9f\u57fa\u5316\u76f4\u63a5\u5f62\u6210\u9ed1\u8272\u4e8c\u6c27\u5316\u949b\u3002<\/p>\n

f. \u7535\u5f27\u7194\u5316\u5904\u7406<\/p>\n

\u5c06\u9996\u5148\u5c06\u6c27\u5316\u7269\u7c89\u672b\u6210\u9897\u7c92\uff0c\u7136\u540e\u5c06\u5176\u7f6e\u4e8e\u5177\u6709\u586b\u5145\u6709Ar\u7684\u5c01\u95ed\u5ba4\u7684\u7535\u5f27\u7089\u4e2d\u3002\uff08Adv. Mater. 2015, 27, 2589\u20132594\uff09\u9ad8\u6e29\u7535\u5f27\u5c06\u91d1\u5c5e\u6c27\u5316\u7269\u9897\u7c92\u52a0\u70ed\u5230\u7194\u70b9\u51e0\u79d2\u949f\uff0c\u7136\u540e\u5feb\u901f\u51b7\u5374\u81f3\u5ba4\u6e29\u3002\u8fd9\u79cd\u5feb\u901f\u7194\u878d\u548c\u51b7\u5374\u8fc7\u7a0b\u6709\u6548\u5730\u56fa\u5b9a\u4e86\u6c27\u5316\u7269\u4e2d\u9ad8\u5ea6\u6d53\u7f29\u7684\u7f3a\u9677\u3002<\/p>\n

\"\u5982\u4f55\u5408\u6210\u6c27\u7a7a\u4f4d\uff1f\u63d2\u56fe2\"\u200b<\/p>\n

g. \u5408\u6210\u65b9\u6cd5\u603b\u7ed3<\/p>\n

\u6839\u636e\u76ee\u524d\u6587\u732e\u62a5\u9053\uff0c\u6c22\u8fd8\u539f\u5904\u7406\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\uff0c\u6210\u4e3a\u5408\u6210\u6c27\u7a7a\u4f4d\u5e7f\u6cdb\u7684\u65b9\u6cd5\u3002\u5229\u7528\u8be5\u65b9\u6cd5\u53ef\u4ee5\u4f7f\u4e8c\u6c27\u5316\u949b\u3001\u4e8c\u6c27\u5316\u9506\u3001\u4e8c\u6c27\u5316\u9530\u3001\u4e09\u6c27\u5316\u94bc\u3001\u4e09\u6c27\u5316\u94a8\u7b49\u4e00\u7cfb\u5217\u91d1\u5c5e\u6c27\u5316\u7269\u4ea7\u751f\u5177\u6709\u9ad8\u8d28\u91cf\u7684\u7f3a\u6c27\u7ed3\u6784\u3002\u4f46\u8be5\u65b9\u6cd5\u53ef\u5728\u9ad8\u6e29\u6216\u9ad8\u538b\u6761\u4ef6\u4e0b\u8fd0\u884c\uff0c\u65e2\u4e0d\u65b9\u4fbf\u3001\u8017\u65f6\u3002\u5316\u5b66\u8fd8\u539f\u5242\u5904\u7406\u4f5c\u4e3a\u6d3b\u6027\u6eb6\u6db2\u8fd8\u539f\u548c\u5ba4\u6e29\u5de5\u827a\u4e5f\u662f\u4e00\u79cd\u5e38\u89c1\u800c\u6709\u6548\u7684\u65b9\u6cd5\uff0c\u4f46\u5b83\u53d7\u5230\u6c27\u7a7a\u4f4d\u542b\u91cf\u76f8\u5bf9\u8f83\u4f4e\u7684\u9650\u5236\u3002\u901a\u8fc7\u6d3b\u6027\u91d1\u5c5e\u8fd8\u539f\u65b9\u6cd5\uff0c\u53ef\u4ee5\u5f97\u5230\u5bcc\u6c27\u539f\u7a7a\u4f4d\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u4f46\u5176\u64cd\u4f5c\u8fc7\u7a0b\u901a\u5e38\u5f88\u590d\u6742\u3002<\/p>\n

\u9ad8\u80fd\u7c92\u5b50\u8f70\u51fb\u3001\u7145\u70e7-\u771f\u7a7a\u6fc0\u6d3b\u548c\u8d85\u58f0\u6ce2\u5904\u7406\uff0c\u5176\u5e94\u7528\u8303\u56f4\u6709\u9650\uff0c\u53ea\u6709\u901a\u8fc7\u8fd9\u4e9b\u65b9\u6cd5\u624d\u80fd\u5408\u6210\u4e00\u5c0f\u90e8\u5206\u5177\u6709\u6c27\u7a7a\u4f4d\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u3002\u6b64\u5916\uff0c\u5236\u5907\u6761\u4ef6\u5bf9\u6c27\u7a7a\u4f4d\u7684\u5f62\u6210\u6709\u91cd\u5927\u5f71\u54cd\uff0c\u5177\u4f53\u8ba8\u8bba\u548c\u603b\u7ed3\u5982\u4e0b\u3002\u5728\u6c22\u8fd8\u539f\u65b9\u6cd5\u4e2d\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u7684\u6c27\u7a7a\u4f4d\u7684\u542b\u91cf\u968f\u7740\u6e29\u5ea6\u548c\u6c22\u538b\u529b\u7684\u5347\u9ad8\u800c\u589e\u52a0\uff0c\u540c\u65f6\u989c\u8272\u4ece\u5149\u5230\u6697\u53d1\u751f\u660e\u663e\u53d8\u5316\u3002\u968f\u7740\u8fd8\u539f\u5242\u91cf\u7684\u589e\u52a0\uff0c\u6c27\u7a7a\u4f4d\u6d53\u5ea6\u76f8\u5e94\u589e\u52a0\u3002\u7136\u800c\uff0c\u8fc7\u91cf\u7684\u8fd8\u539f\u5242\u53ef\u80fd\u4f1a\u5bfc\u81f4\u65b0\u76f8\u751a\u81f3\u91d1\u5c5e\u5355\u8d28\u76f8\u7684\u51fa\u73b0\u3002\u6b64\u5916\uff0c\u5236\u9020\u7f3a\u9677\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u53cd\u5e94\u65f6\u95f4\u4e0e\u7f3a\u9677\u7684\u91cf\u5448\u6b63\u76f8\u5173\u3002<\/p>\n

5.\u6c27\u7a7a\u4f4d\u8868\u5f81\u65b9\u6cd5<\/p>\n

\u5728\u539f\u5b50\u548c\u5206\u5b50\u6c34\u5e73\u4e0a\u6784\u5efa\u7406\u8bba\u6a21\u578b\uff0c\u4ee5\u5206\u6790\u7535\u5b50\u7ed3\u6784\u7684\u53d8\u5316\u548c\u8bc4\u4f30\u8f7d\u6750\u6599\u7684\u50ac\u5316\u673a\u5236<\/p>\n

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